Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO

Mousavi, Seyed Esmaeil; Bozorgian, Alireza

doi:10.22034/ijnc.2020.121743.1096

Document Type : Research Paper

Authors

Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran

https://doi.org/10.22034/ijnc.2020.121743.1096

Abstract

In this study, the kinetics of gas hydrate formation in the presence of tetra-n-butyl ammonium fluoride (TBAF) and cetyl trimethyl ammonium bromide surface active ingredient (CTAB) with zinc nano oxide (ZnO) are investigated and the most important kinetic parameters of hydrate formation such as their induction time and storage capacity were measured. The kinetic experiments were carried out in a constant volume temperature method in a high pressure reactor. The storage capacity of carbon dioxide hydrate in water in the presence of ZnO and surfactants at different temperatures, pressures and concentrations of TBAF and CTAB additives was calculated and measured using time induction measurements. The results show that with increasing pressure and decreasing temperature, the storage capacity of CO2 in hydrate increases. Finally, statistical analysis of the parameters affecting the induction time of hydrate formation showed that zinc oxide can reduce the induction time of hydrate formation compared to other additives.

Keywords

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International Journal of New Chemistry

Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO

References

References

Volume 7, Issue 3
July 2020
Pages 195-219

Investigation the Kinetics of CO2 Hydrate Formation in the Water System + CTAB + TBAF + ZnO

References

References

Volume 7, Issue 3July 2020Pages 195-219

Volume 7, Issue 3
July 2020
Pages 195-219