Synthesis, Characterization, and Application of Zr,Ce-TiO2/SiO2 Nanocomposite Thin Film as Visible-light Active Photocatalyst

Samadi, Susan; Ahmadi, Roya; Kohi, Mehdi

doi:10.22034/ijnc.2015.15630

Synthesis, Characterization, and Application of Zr,Ce-TiO2/SiO2 Nanocomposite Thin Film as Visible-light Active Photocatalyst

Document Type : Research Paper

Authors

Susan Samadi

Roya Ahmadi

Mehdi Kohi

Department of Chemistry, College of Basic Science, Yadegar – e- Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran

https://doi.org/10.22034/ijnc.2015.15630

Abstract

A novel Zr,Ce-TiO₂/SiO₂ nanocomposite thin film was successfully prepared with various amounts of Zr⁴⁺ and Ce⁴⁺ as codopant ions for self-cleaning applications. A thin film was coated on a tile substrate by dip-coating and porous Zr,Ce-TiO₂/SiO₂ was obtained after heat treatment for 2 hours at 500 ^°C. The SEM images and XRD pattern showed that the optimum amount of doping ions in relation to Ti³⁺ is 0.1%. In this circumstance, the most monotony of film was seen and the main formed phase was anatase. The sample structures were characterized by infrared spectroscopy. The nanocomposite films were found to be active for photocatalytic decomposition of methyl orange as an organic pollutant.

Keywords

Codoped TiO2

Photocatalytic application

Self-cleaning

Visible light

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