Thermodynamic-Biochemical Study of Complexes of Intermediate Elements with α-Amino Acids in Some Proteins with Active Site

Tkach, Olduz

doi:10.22034/ijnc.2017.35323

Document Type : Research Paper

Author

Olduz Tkach

Department of Chemistry, School of Engineering, Presidency University, Bengaluru-560064, India.

https://doi.org/10.22034/ijnc.2017.35323

Abstract

In this paper, the quantum chemistry calculations related to the structural parameter of the chromite and molybdate anions and the complexes obtained from them with the glycine and alanine amino acids were performed. The calculations were carried out using HF and DFT methods and in the base series 6-31G *. Thermodynamic studies related to the formation of complexes have been considered and their equilibrium constant has been calculated. Finally, by comparing the thermodynamic factors, the stability of the complexes was determined relative to each other.

Keywords

References

[1] M. Outokesh, A. Tayyebi, A. Khanchi, F.Grayeli, G. Bagheri, J. Microencapsulation, 28(4), 248 (2011).

[2] J.G. Lambardino, E.H. Wiseman, J. Med.Chem., 17, 1182 (1974).

[3] A. Puratchikody,M. Doble, Bioorg. Med. Chem. Lett., 15, 1083 (2007).

[4] M. Antolini, A. Bozzoli, C. Ghiron, Bioorg.Med. Chem. Lett., 9, 1023 (1999).

[5] L. Wang, K.W. Woods, Q. Li, J. Med.Chem., 45, 1697 (2002).

[6]M. Y.Pathan,V. V. Paike, P. R.Pachmase, S.P.More,S. S. Ardhapure, R. P. Pawar, Arkivoc, Part (xv), 205 (2006).

[7] J.C. Lee, J.T. Laydon, P.C. McDonnell, Nature, 372, 739 (1994).

[8] T. Maier, R. Schmierer, K. Bauer, U. S. Patent 4820335 (1989); Chem. Abstr., 111, 19494 (1989).

[9] R. Schmierer, H. Mildenberger, H. Buerstell, German Patent 361464 (1987);

Chem. Abstr., 108, 37838 (1988).

[10] P. Wasserscheid, W. Keim, Angew. Chem.Int. Ed. Eng., 39, 37872 (2000).

[11] I. Satoru, Japn Kokkai Tokyo Koho JP 01, 117, 867, May 10, 1989; Chem. Abstr., 111, 214482 (1989).

[12] S. Samai, G.C. Nandi, P. Singh, Tetrahedron, 65, 10155 (2009).

[13] S.A.A. Mansour, K.U. Sadek, Chin. Chem. Lett., 20, 812 (2009).

International Journal of New Chemistry

Thermodynamic-Biochemical Study of Complexes of Intermediate Elements with α-Amino Acids in Some Proteins with Active Site

References

References

Volume 4, Issue 2
April 2017
Pages 39-43

Thermodynamic-Biochemical Study of Complexes of Intermediate Elements with α-Amino Acids in Some Proteins with Active Site

References

References

Volume 4, Issue 2April 2017Pages 39-43

Volume 4, Issue 2
April 2017
Pages 39-43