International Journal of New Chemistry
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Increasing the catalytic property of tributylhexadecylphosphonium bromide through the displacement of anions and comparing its catalytic activity in the synthesis of some organic compounds

Document Type : Research Paper

Authors

Leila Mohammadi 1, 1
Rashid Badri 1
Alireza Kiasat 2

1 Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz,Iran

2 Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz, Iran

https://doi.org/10.22034/ijnc.2024.2036666.1407
Abstract
In this study, the combination of tributylhexadecylphosphonium bromide (TBHDPB) was chosen as an effective catalyst in the one-pot synthesis of 3, 4-dihydropyrimidinone (thione). This compound was reacted with potassium peroxypersulfate and persulfate anion (S2O82-) was introduced instead of bromide ion in tributylhexadecylphosphonium bromide compound and tributylhexadecylphosphonium peroxypersulfate compound was formed with two sites to activate the reactants. It was used in the synthesis of dihydropyrimidinones and imidazoles. It was found that the catalytic activity of tertylhexadecylphosphonium bromide was improved through the replacement of Br- bromide anion with K2S2O8 anion.

The mentioned catalysts accelerated the synthesis of dihydropyrimidinone derivatives and imidazoles through condensation reactions and cyclization of compounds related to synthesis at appropriate temperature. The low cost and accessibility of the catalyst, the simplicity of the method of use, the mild reaction conditions are the important advantages of this research.

The obtained compounds were identified by FT-IR, 1HNMR and 13CNMR spectroscopy as well as melting point measurement and comparison with the reported compounds.

Keywords

Tributyl hexadecyl phosphonium persulfate
dihydropyrimidinone (thion)
imidazole
Subjects
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International Journal of New Chemistry
Volume 12, Issue 1
Winter 2025
Pages 23-52

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