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Advances in Green Chemistry: Sustainable Approaches in Organic Synthesis

Document Type : Review

Author

* Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Shahre-rey Branch, Islamic Azad University, Tehran, Iran.

Abstract
Green chemistry has emerged as a transformative approach to addressing the pressing environmental challenges posed by traditional chemical processes. This review paper, titled "Advances in Green Chemistry: Sustainable Approaches in Organic Synthesis," explores the latest innovations and methodologies that align with the principles of sustainability and environmental stewardship. The field of organic synthesis, a cornerstone of chemical science, has historically relied on resource-intensive and hazardous processes. However, recent advancements have introduced eco-friendly alternatives that minimize waste, reduce energy consumption, and eliminate the use of toxic reagents. This paper highlights key developments such as catalysis-driven transformations, the use of renewable feedstocks, solvent-free and aqueous-phase reactions, and the integration of green technologies like flow chemistry and biocatalysis. Additionally, it examines the role of computational tools and machine learning in optimizing reaction conditions to enhance efficiency and sustainability. By providing a comprehensive overview of these advancements, this review underscores the critical importance of green chemistry in fostering a more sustainable future for organic synthesis while addressing global environmental and economic concerns. The paper also identifies current challenges and potential avenues for future research, emphasizing the need for interdisciplinary collaboration to further revolutionize the field.

Keywords

Subjects

  1. Yang, X. Chen, J. Guan, et al., Catal. Today 246, 176 (2015).
  2. Á. Molnár, A. Sárkány, and V. Varga, Mol. Catal. A 173, 185 (2001).
  3. Bonrath, J. Medlock, J. Schütz, et al., Hydrogenation, 66 (2012).
  4. M. Kluwer, T. S. Koblenz, T. Jonishkeit, et al., Am. Chem. Soc. 127, 15470 (2005).
  5. Rahsepar and H. Kim, J. Alloys Compd. 649, 1323 (2015).
  6. A. Redina, A. A. Greish, I. V. Mishin, et al., Catal. Today 241, 246 (2015).
  7. P. Beletskaya and L. M. Kustov, Russ. Chem. Rev. 79, 441 (2010).
  8. F. Sels and L. M. Kustov, Zeolites and Zeolite-like Materials(Elsevier, Amsterdam, 2016), p. 1.
  9. Ashoka and R. Hari Krishna, in Green Sustainable Process for Chemical and Environmental Engineering and Science(Elsevier, Amsterdam, 2021), Chap. 1, p. 1.
  10. Bian and S. Kawi, Catal. Today 339, 3 (2020).
  11. L. Wang, X. Q. Ban, L. Q. Xie, et al., ACS Sustain. Chem. Eng. 7, 1989 (2019).
  12. Yu, Y. S. Yang, L. F. Chen, et al., Appl. Catal. B: Environ. 277, 119273 (2020).
  13. L. H. Wang, Chem. Phys. Lett. 757, 137871 (2020).
  14. Aguilar-Tapia, L. Delannoy, C. Loui, et al., J. Catal. 344, 515 (2016).
  15. Narani, H. P. R. Kannapu, K. Natte, et al., Mol. Catal. 497, 111200 (2020).
  16. Kirichenko, G. Kapustin, V. Nissenbaum, et al., J. Therm. Anal. Calorim. 134, 233 (2018).
  17. Kirichenko, G. Kapustin, V. Nissenbaum, et al., J. Therm. Anal. Calorim. 118, 749 (2014).
  18. Liu, H. Wang, J. Shen, Y. Sun, and Z. Liu, Appl. Catal. A 337, 138 (2008). https://doi.org/10.1016/j.apcata.2007.12.006
  19. P. Feynman, Caltech Eng. Sci. 23(5), 22 (1960). http://www.zyvex.com/nanotech/feynman.html
  20. Steiner, Semiconductor Nanostructures for Opto-Electronic Applications(Artech House, Boston, 2004).
  21. Nanoscale, National Nanotechnology Initiative. http://www.nano gov/nanotech-101/what/nano-size.
  22. M. Naidu, A Textbook of Applied Physics(Pearson Education, India, 2009).
  23. Alagarasi, in Advances in Nanomaterials(Springer, India, 2016), p. 76.
  24. p. Nikalje, Med. Chem. 5, 081 (2015). https://doi.org/10.4172/2161-0444.1000247
  25. Allsopp, A. Walters, and D. Santillo, Nanotechnologies and Nanomaterials in Š•lectrical and Š•lectronic Goods(Greenpeace Res. Labor., 2007).
  26. Rashidi and K. K. Darani, Crit. Rev. Food Sci. Nutr. 51, 723 (2011). https://doi.org/10.1080/10408391003785417
  27. Wang, X. Chen, X. Ma, H. Zheng, M. Ji, and Z. Zhang, Chem. Phys. Lett. 384, 391 (2004).
  28. Chen and L. Gao, Chem. Phys. Lett. 395, 316 (2004). https://doi.org/10.1016/j.cplett.2004.07.102
  29. Giri, S. Samanta, S. Maji, S. Ganguli, and A. Bhaumik, J. Magn. Magn. Mater. 285, 296 (2005).
  30. Peng, T. Xie, Z. Fan, Q. Zhao, D. Wang, and D. Zhang, Chem. Phys. Lett. 459, 159 (2008).
  31. Nuli, P. Zhang, Z. Guo, P. Munroe, and H. Liu, Electrochim. Acta 53, 4213 (2008). https://doi.org/10.1016/j.electacta.2007.12.067
  32. Liu, J. Guo, Y. Cheng, Y. Li, G. Xu, and P. Cui, J. Cryst. Growth 311, 147 (2008).
  33. Mandal and A. H. E. Muller, Mater. Chem. Phys. 111, 438 (2008). https://doi.org/10.1016/j.matchemphys.2008.04.043
  34. Xu and A. S. Teja, J. Supercrit. Fluids 44, 85 (2008). https://doi.org/10.1016/j.supflu.2007.09.001
  35. Chen, Y. Zhao, M. Yang, J. He, P. K. Chu, J. Zhang, and S. Wu, Anal. Chim. Acta 659, 266 (2010). https://doi.org/10.1016/j.aca.2009.11.040
  36. Song, S. Zhang, B. Chen, J. Ge, and X. Jia, Colliods Surf., A 360, (2010). https://doi.org/10.1016/j.colsurfa.2012.05.039
  37. Sun, L. You, D. Wang, Y. Sun, J. Ma, and G. Lu, Sens. Actuators, B 156, 368 (2011). https://doi.org/10.1016/j.snb.2011.07.043
  38. K. Maji, N. Mukherjee, A. Mondal, and B. Adhihary, Polyhedron 33, 145 (2012).
  39. Sun, W. Wang, Y. Liu, Y. Sun, J. Ma, and G. Lu, Sens. Actuators, B 173, 52 (2012). https://doi.org/10.1016/j.snb.2012.05.057
  40. Umar, M. S. Akhtar, G. N. Dar, and S. Baskoutas, Talanta 116, 1060 (2013). https://doi.org/10.1016/j.talanta.2013.08.026
  41. Kumar, Surf. Eng. 38, 324 (2022). https://doi.org/10.1080/02670844.2022.2073424
  42. Kumar and R. Kumar, Surf. Eng. 37(11), 1 (2021). https://doi.org/10.1080/02670844.2021.1967024 
  43. Kumar, A. Handa, V. Chawla, N. K. Grover, and R. Kumar, Surf. Eng. 37(5), 1 (2021). https://doi.org/10.1080/02670844.2021.1924506 
  44. Kumar, M. Kumar, and A. Handa, Mater. Res. Express 6, 125533 (2019). https://doi.org/10.1088/2053-1591/ab5fae
  45. B. Goudjil, H. Dali, S. Zighmi, Z. Mahcene, and S. E. Benchiekh, Desalin. Water Treatm. 317, 100079 (2024). https://doi.org/10.1016/j.dwt.2024.100079
  46. T. Geldasa, M. A. Kebede, M. W. Shura, and F. G. Hone, RSC Adv. 13, 18404 (2023). https://doi.org/10.1039/D3RA01505J